TY - BOOK AU - Al-Ramadhani, Omar Mowafaq Younis PY - 2016 DA - 2016// TI - Synthesis and characterization of new CN-based transition metal complexes PB - Universität Rostock CY - Rostock AB - In the first part of this thesis the coordination behavior for P(CN)3 was studied, for preparing CN-rich phosphorous compounds from the reaction of P(CN)3 with weakly coordinating anions, Lewis bases, transition metal complexes and room temperature ionic liquids. In the second part of this thesis the new transition metal complexes from tetracyanopyrrole were synthesized. Remarkably, a new 1D-coordination polymer based on tetracyanopyrrolide could be isolated. Additionally, new TCP-salts of the type [R3NH]TCP (R= Me or nPr) were synthesized. All synthesized compounds were fully characterized. UR - http://purl.uni-rostock.de/rosdok/id00001837 UR - https://doi.org/10.18453/rosdok_id00001837 DO - 10.18453/rosdok_id00001837 LA - English N1 - vorgelegt von Omar Mowafaq Younis Al-Ramadhani ID - 876717504 ER -