TY  - BOOK
AU  - Bresien, Jonas
PY  - 2016
DA  - 2016//
TI  - Synthesis and characterisation of cyclic polyphosphanes
PB  - Universität Rostock
CY  - Rostock
AB  - The synthesis and reactivity of the novel cyclotetraphosphane [ClP(μ-PMes*)]2 were studied. The cyclophosphane proved to be a versatile reagent in phosphorus chemistry, since its Cl-functionalised P4 backbone could be used as a building block in a variety of reactions with Lewis acids, bases as well as reducing agents. The rearrangement of P−P bonds as well as a 1,2-Cl shift were identified as common reaction pathways to stabilise the products. All synthesised compounds were fully characterised, including experimental and theoretical methods.<eng>
UR  - http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2016-0091-5
LA  - English
N1  - submitted by Jonas Bresien
ID  - 865466955
ER  -