TY  - BOOK
AU  - Pérez Vélez, Roxana
PY  - 2014
DA  - 2014//
TI  - Structural characterization of iron species in Fe-ZSM-5 catalysts and the elucidation of their role in the mechanism of NOx reactions
AB  - The selective catalytic reduction of NOx by ammonia (NH3-SCR) has widely applied in the abatement of NOx. Fe-ZSM-5 is a potential catalyst, showing high performance in standard SCR (mainly NO) at > 400°C and in fast SCR (NO/NO2 = 1) at ≥ 250°C. The identification of the active species in Fe-ZSM-5 catalysts and reaction mechanism for SCR reactions were investigated by in situ and operando EPR, UV-Vis and FTIR spectroscopy. The spectroscopic studies demonstrate the role of NO2 to reoxidize isolated Fe(II) to the active Fe(III) at β and γ sites, and attribute them the higher activity in fast SCR.
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0041-9
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0041-9&pdf
UR  - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0041-9
LA  - English
N1  - vorgelegt von : Roxana Pérez Vélez
ID  - 818337222
ER  -