TY  - BOOK
AU  - Domke, Lutz
PY  - 2014
DA  - 2014//
TI  - Asymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefins
AB  - Asymmetric hydrogenation as well as hydroformylation of 1,1-disubstituted olefins were investigated. Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high stereoselectivities. Furthermore, the rhodium-catalyzed asymmetric hydroformylation of an alpha-phosphorylated styrene derivative was examined and the scope could be expanded using new phosphite-phosphoramidite ligands. In addition, HP-NMR experiments gave some indication of the active catalyst-complex.
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0026-6
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0026-6&pdf
UR  - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0026-6
LA  - English
N1  - vorgelegt von Lutz Domke
ID  - 817979794
ER  -