TY - BOOK AU - Tengho Toguem, Serge-Mithérand PY - 2011 DA - 2011// TI - Twofold Heck AB - This thesis presents site-selective Suzuki-Miyaura reactions of 2,3,5-tribromo-thiophene, 2,4,5-tribromothiophene and 2,3,5-tribromo-N-methylpyrrole, which are controlled by steric and electronic parameters. Palladium-catalyzed Heck reactions of brominated thiophenes, N-methylimidazole, N-methylpyrrole and N-methylindole are also presented. The products were transformed by subsequent 6p-electrocyclization and dehydrogenation to functionalized benzothiophenes, dibenzothiophenes, benzimidazoles, indoles and carbazoles, respectively. UR - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2012-0025-5 UR - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2012-0025-5&pdf UR - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2012-0025-5 LA - English N1 - 6π-electrocyclization and regioselective palladium(0)-catalyzed reactions of brominated thiophenes, pyrroles, imidazoles and indoles / vorgelegt von Serge-Mithérand Tengho Toguem ID - 687893097 ER -