TY  - BOOK
AU  - Zhou, Shaolin
PY  - 2011
DA  - 2011//
TI  - Development of new homogeneous (enantioselective) hydrogenation catalysts based on bio-relevant metals
AB  - This thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Brønsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. Finally, an iron cluster catalyst was discovered to catalyze the reduction of amides with inexpensive PMHS.
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7&pdf
UR  - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0127-7
LA  - English
N1  - vorgelegt von Shaolin Zhou
ID  - 66775279X
ER  -