TY - BOOK AU - Nawaz, Muhammad PY - 2010 DA - 2010// TI - Synthesis of functionalized benzophenones and terphenyls based on site-selective Suzuki-Miyaura reactions of Bis(triflates) of various hydroxylated benzophenones and benzoates AB - The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflates) of 2,4'-dihydroxybenzophenones afforded 2,4'-diarylbenzophenones. The Suzuki-Miyaura reaction of the bis(triflate) of 3,4-dihydroxybenzophenone with two equivalents of boronic acids gave 3,4-diarylbenzophenones. The Sonogashira cross-coupling reactions of the same substrate display remarkable compatibility with Suzuki reactions.The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflates) of methyl 2,5-dihydroxybenzoate and methyl 2,4-dihydroxybenzoate afforded p-terphenyls and m-terphenyls respectively. UR - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0067-4 UR - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0067-4&pdf UR - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0067-4 UR - http://d-nb.info/1014240336/34 UR - http://rosdok.uni-rostock.de/file/rosdok_derivate_000000004606/Dissertation_Nawaz_2011.pdf LA - English N1 - vorgelegt von Muhammad Nawaz ID - 65814720X ER -