TY - BOOK AU - Adamovski, Serguei PY - 2010 DA - 2010// TI - calorimetric study of non-equilibrium structures on fast cooling (100 000 K/s) AB - Present work describes an ultra-fast scanning calorimeter that is capable of controlled cooling and heating at rates up to 100 000 K/s as well as isothermal measurements with time resolution of 0.1 ms. The technique was applied to study crystallization kinetics of polymers and monodisperse n-alkanes. It is shown that the bend in the isothermal crystallization kinetics curve of n-alkanes is not the transition between formations of structures with different folding indexes, but it is rather caused by the interplay of different processes with different kinetics as well as a self-poisoning effect. UR - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0196-0 UR - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0196-0&pdf UR - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2010-0196-0 UR - http://d-nb.info/1011895897/34 UR - http://rosdok.uni-rostock.de/metadata/rosdok_disshab_000000000563 LA - English N1 - submitted by Serguei Adamovski ID - 642884315 ER -