TY  - BOOK
AU  - Torborg, Christian
PY  - 2009
DA  - 2009//
TI  - Application of novel phosphine ligands in palladium-catalyzed cross-coupling reactions
AB  - This thesis describes the application of 2-phosphino-N-aryl-heterocycles as ligands in Pd-catalyzed CC, CN and CO bond forming reactions. Based on prior studies, 2-phosphino-N-arylindoles and -pyrrols were found to form efficient catalysts with Pd-salts in the Sonogashira coupling of (hetero)aryl bromides and the Pd-catalyzed monoarylation of ammonia. The novel imidazole-based phosphines were prepared after a modular synthesis and are stable towards air. They were employed in the Pd-catalyzed phenol synthesis, the Heck-Cassar coupling, and the Pd-catalyzed monoarylation of ammonia. Furthermore, mechanistic studies in the Pd-catalyzed hydroxylation were undertaken.
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3&pdf
UR  - http://rosdok.uni-rostock.de/file/rosdok_derivate_000000004073/Dissertation_Torborg_2009.pdf
UR  - http://d-nb.info/999072188/34
UR  - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2009-0174-3
LA  - English
N1  - vorgelegt von Christian Torborg
ID  - 610628437
ER  -