TY  - BOOK
AU  - Enthaler, Stephan
PY  - 2007
DA  - 2007//
TI  - New aspects in homogeneous hydrogenation: development of practical rhodium phosphine catalysts and environmentally benign iron catalysts
AB  - This dissertation deals with the application of monodentate phosphine ligands in asymmetric hydrogenation of CC double bonds. The usefulness of rhodium catalysts containing phosphines based on the 4,5Dihydro3Hdinaphtho[2,1c;1,́2́e]phosphepine scaffold was demonstrated in the reduction of various prochiral substrates, since excellent enantioselectivities up to 96% ee were achieved. Furthermore, the properties of ironbased catalysts were studied in the field of transfer hydrogenation. Here high catalyst activities up to 2500 h-1 were obtained in the reduction of ketones.
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2008-0008-7
UR  - http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2008-0008-7&pdf
UR  - http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2008-0008-7
LA  - English
N1  - vorgelegt von Stephan Enthaler
ID  - 562031685
ER  -