TY - BOOK AU - Ahrens, Sebastian PY - 2025 DA - 2025// TI - Rational design and synthesis of phosphine ligands and their application in transition metal-catalyzed reactions PB - Universität Rostock CY - Germany; Rostock AB - This work reports the development of novel ligand and catalyst systems for selected transition metal-catalyzed reactions. The synthesis of (benzo-)furylphosphine ligands enabled the development of highly efficient cobalt catalysts for the isomerization of allylamines to enamines. Furthermore, the developed ligands were successfully applied in the palladium-catalyzed telomerization of 1,3-butadiene. In addition, ruthenium-based catalyst systems enabling the selective deuterium labeling of pharmaceutically relevant 2-propylbenzimidazole derivatives are presented. UR - https://purl.uni-rostock.de/rosdok/id00005821 UR - https://doi.org/10.18453/rosdok_id00005821 DO - 10.18453/rosdok_id00005821 LA - English N1 - vorgelegt von Sebastian Ahrens ID - 1986237281 ER -