TY  - BOOK
AU  - Kushik
PY  - 2025
DA  - 2025//
TI  - Phosphaalkene ligands: a new perspective on Wittig-type transformations
PB  - Universität Rostock
CY  - Germany; Rostock
AB  - This thesis comprises four parts. First, attempts to synthesize phosphaalumenes using phospha‑Wittig reagents and Al(I) sources revealed transient intermediates that deactivate via dimerization or C–H activation. Second, a new azide‑Wittig reaction forms triazabutadienes from azides and aldehydes under mild conditions with broad scope. Third, bis‑phosphaalkene P,N,P ligands from carbazole give strong donors. Finally, Rh(I) complexes show distinct coordination and C–H activation, expanding phospha‑Wittig chemistry.<eng>
UR  - https://purl.uni-rostock.de/rosdok/id00005664
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005664-5
UR  - https://d-nb.info/1412027020/34
UR  - https://doi.org/10.18453/rosdok_id00005664
DO  - 10.18453/rosdok_id00005664
LA  - English
N1  - vorgelegt von Kushik
ID  - 1979519145
ER  -