TY  - BOOK
AU  - Nasrullah, Ayu Afiqah
PY  - 2025
DA  - 2025//
TI  - The  chemistry of cyanophosphide and phosphafluorene: insights into structure and reactivity
PB  - Universität Rostock
CY  - Germany; Rostock
AB  - This thesis explores low-valent phosphorus chemistry using sterically demanding terphenyl (DippTer) substituents. It establishes the cyanophosphide [DippTerPCN]⁻ as a versatile platform, exhibiting the first P–CN/NC coordination isomerism upon O₂ oxidation and transfer reactivity to GeCl₂ (forming chlorogermylenes) and PCl₃/AsCl₃. A related DippTer-phosphafluorene enables Frustrated Lewis Pair (FLP) activation of terminal alkynes, yielding zwitterionic alkenyl phosphonium borates.<eng>
UR  - https://purl.uni-rostock.de/rosdok/id00005658
UR  - https://doi.org/10.18453/rosdok_id00005658
DO  - 10.18453/rosdok_id00005658
LA  - English
N1  - vorgelegt von Ayu Afiqah Nasrullah
ID  - 1976005590
ER  -