TY - BOOK AU - El-Sepelgy, Osama PY - 2025 DA - 2025// TI - Bio-inspired sustainable catalysis with base-metals and visible light PB - Universität Rostock CY - Rostock AB - This thesis explores biomimetic catalytic systems inspired by metalloenzymes, utilizing ligand-to-metal charge transfer (LMCT) and metal-ligand cooperation (MLC) to enable efficient 3d-metal catalysis. By using earth-abundant metals, these approaches mimic enzymatic mechanisms where ligands actively participate in reactions. It covers cobalt catalysis for visible-light-induced radical desaturation and manganese pincer complexes for various redox transformations. The research integrates experimental and theoretical studies to optimize sustainable catalytic systems. UR - https://purl.uni-rostock.de/rosdok/id00005152 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005152-3 UR - https://d-nb.info/1393157084/34 UR - https://doi.org/10.18453/rosdok_id00005152 DO - 10.18453/rosdok_id00005152 LA - English N1 - vorgelegt von Dr. Osama El-Sepelgy ID - 1963633202 ER -