TY  - BOOK
AU  - Li, Sihan
PY  - 2024
DA  - 2024//
TI  - Highly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienes
PB  - Universität Rostock
CY  - Rostock
AB  - The first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.<eng>
UR  - https://purl.uni-rostock.de/rosdok/id00004877
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004877-8
UR  - https://d-nb.info/137315067X/34
UR  - https://doi.org/10.18453/rosdok_id00004877
DO  - 10.18453/rosdok_id00004877
LA  - English
N1  - vorgelegt von Sihan Li
ID  - 1931412952
ER  -