TY  - BOOK
AU  - Tönjes, Jan Günther
PY  - 2024
DA  - 2024//
TI  - P(III)/P(V) redox cycling catalysis: advances in catalytic Wittig and Appel reactions
PB  - Universität Rostock
CY  - Rostock
AB  - P(III)/P(V) redox cycling catalysis avoids phosphine oxide waste in reactions by reducing it in situ using silanes as terminal reductants. New methods were developed. In a catalytic base-free Wittig (BFW) reaction highly substituted alkenes were formed using environmentally friendly PMHS. An intermediate of the BFW was scavenged with acyl chlorides. Activated alkenes could thus be converted to furans with an unusual substitution pattern. Alcohols and epoxides were converted stereospecifically in a catalytic Appel chlorination under low catalyst loading using small amounts of hexachloroacetone.<eng>
UR  - https://purl.uni-rostock.de/rosdok/id00004760
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004760-8
UR  - https://d-nb.info/1361954388/34
UR  - https://doi.org/10.18453/rosdok_id00004760
DO  - 10.18453/rosdok_id00004760
LA  - English
N1  - vorgelegt von Jan Günther Tönjes
ID  - 1920808655
ER  -