TY  - BOOK
AU  - Cisneros, Sebastian
PY  - 2023
DA  - 2023//
TI  - Structure-reactivity relationships in heterogeneous catalytic CO2 hydrogenation to CH4 and CO on low loaded precious metal catalysts
PB  - Universität Rostock
CY  - Rostock
AB  - The production of CH4 and CO via CO2 hydrogenation was studied on catalysts with low precious metal loading. CO2 methanation was investigated on Ru/TiO2 und Ru/ZrO2 catalysts with Ru < 1 wt.%. CO production was investigated on Au/ZrO2 and Au/TiO2 catalysts with < 0.1 wt.% Au. Notably the most O-defective catalysts showed the highest rates. In-situ spectroscopic assessments revealed distinct electronic metal-support interactions induced by electron transfer from the defects to the supported metal entities. This effect is proposed as driver for the catalytic enhancement.<eng>
UR  - https://purl.uni-rostock.de/rosdok/id00004614
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004614-6
UR  - https://d-nb.info/1334986525/34
UR  - https://doi.org/10.18453/rosdok_id00004614
DO  - 10.18453/rosdok_id00004614
LA  - English
N1  - vorgelegt von Sebastian Cisneros
ID  - 1892116170
ER  -