TY  - BOOK
AU  - Fessler, Johannes
PY  - 2023
DA  - 2023//
TI  - Iron and its neighbors: earth-abundant hydrogenation catalysts for the synthesis of heterocycles and ethers
PB  - Universität Rostock
CY  - Rostock
AB  - This thesis discusses the topic of earth-abundant metals in hydrogenation catalysis. Firstly, a new family of manganese PNN-pincer catalysts was developed for the hydrogenation of quinolines at ambient temperature. Secondly, an iron-Tetraphos system was discovered that allows direct N-aryl pyrrole synthesis from nitroarenes in a  hydrogenation/Paal-Knorr cascade. Lastly, the effect of phosphine oxide promoters on cobalt carbonyl precatalysts was evaluated, leading to improved protocols for the reductive etherification of aldehydes and the reductive or carbonylative transformation of oxetanes.<eng>
UR  - https://purl.uni-rostock.de/rosdok/id00004603
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004603-2
UR  - https://d-nb.info/1332620981/34
UR  - https://doi.org/10.18453/rosdok_id00004603
DO  - 10.18453/rosdok_id00004603
LA  - English
N1  - vorgelegt von Johannes Fessler
ID  - 189062134X
ER  -