TY  - BOOK
AU  - Al-Yusufi, Mohammed Abdullah Ahmed
PY  - 2022
DA  - 2022//
TI  - Selective synthesis of 1,5-pentanediol from furfural derivatives over stable nickel-based catalysts
PB  - Universität Rostock
CY  - Rostock
AB  - Reduced Ni on highly basic lanthanide supports in isopropanol (2-PrOH) was proved to be an efficient catalyst and an economically viable alternative to modified noble metal catalytic systems for the direct hydrogenolysis of tetrahydrofurfuryl alcohol (THFA) and furfural to 1,5-pentanediol (1,5-PeD). For the first time, a continuous catalytic transfer hydrogenolysis (CTH) process for the selective hydrogenolysis of THFA to 1,5-PeD was developed using Ni-La(R) in 2-PrOH. A maximum 1,5-PeD yield of 73% with an productivity of 1.4 mmol g(cat)-1 h-1 was achieved under continuous CTH conditions.<eng>
UR  - https://purl.uni-rostock.de/rosdok/id00004535
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004535-9
UR  - https://d-nb.info/1320976492/34
UR  - https://doi.org/10.18453/rosdok_id00004535
DO  - 10.18453/rosdok_id00004535
LA  - English
N1  - vorgelegt von Mohammed Abdullah Ahmed Al-Yusufi
ID  - 1880511576
ER  -