TY  - BOOK
AU  - Eickhoff, Liesa Henrike
PY  - 2023
DA  - 2023//
TI  - Synthesis and Reactivity of Pacman Phosphanes
PB  - Universität Rostock
CY  - Rostock
AB  - Pacman ligands can coordinate two metal centres and are inter alia used to achieve cooperative reaction behaviour. In this thesis, we transferred the concept to phosphorus chemistry. The substituents remaining on the phosphorus atoms in the resulting Pacman phosphanes strongly influence their properties, leading to the formation of different isomers or in the case of halogenated Pacman phosphanes to highly dynamic systems. During formation of dications by halide abstraction, redox isomerism is observed. Moreover, some of the Pacman phosphanes act as multidentate ligands.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00004406
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004406-9
UR  - https://d-nb.info/1301016373/34
UR  - https://doi.org/10.18453/rosdok_id00004406
DO  - 10.18453/rosdok_id00004406
LA  - English
N1  - vorgelegt von Liesa Henrike Eickhoff
ID  - 1857656997
ER  -