TY  - BOOK
AU  - Zanina, Anna
PY  - 2023
DA  - 2023//
TI  - Fundamentals determining activity and product selectivity in the oxidative coupling of methane over MnOx-M2WO4/SiO2 (M=Na, K, Rb, or Cs)
PB  - Universität Rostock
CY  - Rostock
AB  - The present thesis contributes to a better understanding of one of the most promising catalysts for the oxidative coupling of methane (OCM) reaction, i.e., MnOx-Na2WO4/SiO2. Oxygen species involved in selective and unselective pathways were investigated using O2 and N2O as the oxidants. Spatially resolved and steady-state kinetic analyses combined with oxygen isotopic exchange tests were used to identify the activity-defining descriptor over M2WO4/SiO2 (M=Na, K, Rb, or Cs). The effects of alkali metal for both bi- and trimetallic compositions on activity and selectivity were established<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00004386
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004386-5
UR  - https://d-nb.info/1297583310/34
UR  - https://doi.org/10.18453/rosdok_id00004386
DO  - 10.18453/rosdok_id00004386
LA  - English
N1  - vorgelegt von Anna Zanina
ID  - 1853798460
ER  -