TY - BOOK AU - Bourriquen, Florian Marwan PY - 2022 DA - 2022// TI - Hydrogen / deuterium exchange reactions: small variations for heavy changes PB - Universität Rostock CY - Rostock AB - This dissertation reports the development of new catalytic methodologies for deuterium incorporation into organic molecules. In a first part, the use of a simple Lewis acid is reported for the isotopic labelling of electron-rich (hetero)arenes. Next, two heterogeneous catalysts are presented for the labelling of comparable compounds: a first-generation iron-based system and a follow-up work using manganese. Both materials are easily prepared and fully characterised. Additionally, investigations were performed to gain insight on the mechanisms. UR - http://purl.uni-rostock.de/rosdok/id00004295 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004295-8 UR - https://d-nb.info/1292078758/34 UR - https://doi.org/10.18453/rosdok_id00004295 DO - 10.18453/rosdok_id00004295 LA - English N1 - vorgelegt von Florian Bourriquen ID - 1845697952 ER -