TY  - BOOK
AU  - Kopf, Sara
PY  - 2022
DA  - 2022//
TI  - Development of hydrogen isotope exchange methodologies for the deuteration of aromatic substrates
PB  - Universität Rostock
CY  - Rostock
AB  - This thesis entails the development of practical and cost-efficient deuteration methodologies. The first C–H activation and deuteration of aromatic substrates using an earth-abundant manganese catalyst and transient directing groups was reported. Secondly, the transient directing group strategy was transferred to a ruthenium-catalyzed hydrogen isotope exchange reaction. Lastly, the electronic characteristics of pyridine derivatives were harnessed for a transition metal-free deuteration protocol. The results are expected to inspire future developments in sustainable hydrogen isotope exchange.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00004135
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004135-3
UR  - https://d-nb.info/1293540013/34
UR  - https://doi.org/10.18453/rosdok_id00004135
DO  - 10.18453/rosdok_id00004135
LA  - English
N1  - vorgelegt von Sara Kopf
ID  - 1831239965
ER  -