TY  - BOOK
AU  - Suhrbier, Tim
PY  - 2021
DA  - 2021//
TI  - Synthesis and characterization of a masked N-heterocyclic phosphinidene (NHP)
PB  - Universität Rostock
CY  - Rostock
AB  - This thesis summarizes the synthesis and characterization of an unprecedented heterocyclobutane derivative. To assess the biradical character, quantum mechanical computations were carried out. The second part elaborates on the reactivity (LEWIS acids/bases, an isonitrile, carbon monoxide, chalcogens). Notably, the addition of alkenes/alkynes to form phosphiranes/phosphirenes highlights the phosphinidene-type reactivity. In the last part, heavier congeners (As, Sb, Bi) of chlorinated precursors and theoretical investigations of their corresponding reduced heterocycles is discussed.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00003451
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00003451-3
UR  - https://d-nb.info/1293536296/34
UR  - https://doi.org/10.18453/rosdok_id00003451
DO  - 10.18453/rosdok_id00003451
LA  - English
N1  - vorgelegt von Tim Suhrbier
ID  - 1786999986
ER  -