TY - BOOK AU - Kloß, Svenja PY - 2020 DA - 2020// TI - Influence of the ligand structure on the hydroformylation of olefins PB - Universität Rostock CY - Rostock AB - This thesis deals with the influence of different structural features of phosphorus-containing ligands on the properties of homogeneous catalysts using the example of rhodium catalyzed hydroformylation of alkenes. For this purpose, several phosphites were synthesized. These were tested afterwards as ligands in the hydroformylation of n-octenes. The activity and n-selectivity were evaluated and the stability towards hydrolysis investigated. Two PNP pincer ligands and their rhodium complexes were synthesized. These and a triphosphine were subsequently tested in the hydroformylation of 1-octene. UR - http://purl.uni-rostock.de/rosdok/id00002870 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002870-8 UR - https://d-nb.info/1293661864/34 UR - https://doi.org/10.18453/rosdok_id00002870 DO - 10.18453/rosdok_id00002870 LA - English N1 - vorgelegt von Svenja Kloß ID - 1743360118 ER -