TY - BOOK AU - Ha, Quan Luu Manh PY - 2019 DA - 2019// TI - Development of Ni catalysts with low metal content and improved stability in the dry reforming of methane to syngas PB - Universität Rostock CY - Rostock AB - Catalysts with 2.5 wt% Ni supported on MgO-Al2O3 were developed for CH4 dry reform-ing (DRM) that are stable at either mild (stoichiometric) or severe (CH4-rich) conditions. Solid materials were characterized with suitable methods. Catalysts with NiO-MgO-Al2O3 solid solution were active even at 500 °C. In stoichiometric DRM, Ni catalyst modified with La and citric acid reduced both Ni re-oxidation and agglomeration, preserving high activity over 160 h. Besides, proper support pre-treatment or adding Gd3+ both offered outstandingly coking-resistant Ni-based catalysts for CH4-rich DRM over 100 h. UR - http://purl.uni-rostock.de/rosdok/id00002741 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002741-9 UR - https://d-nb.info/1293660574/34 UR - https://doi.org/10.18453/rosdok_id00002741 DO - 10.18453/rosdok_id00002741 LA - English N1 - vorgelegt von Quan Luu Manh Ha ID - 1727957962 ER -