TY  - BOOK
AU  - Adomeit, Sven
PY  - 2019
DA  - 2019//
TI  - Structure-reactivity relationships in Cu/TEMPO catalyzed aerobic alcohol oxidation: mechanistic assessment by (coupled) operando spectroscopic tools
PB  - Universität Rostock
CY  - Rostock
AB  - Aerobic alcohol oxidation is a route to convert alcohols into aldehydes using homogenous Cu catalysts with O2 as the terminal oxidant. It is well-known that the Cu catalyst forms a Cu(I/II) shuttle during the reaction. To investigate still open issues coupled operando EPR/UV-vis/ATR-IR was used in a first step. Through this combination it was possible to observe distinctive effects of the structure and molar ratios of ligands/additives upon the redox behavior of the Cu(I/II) shuttle. The triple coupling was further developed into a 4-in-1 set-up by implementing X-ray absorption spectroscopy.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00002740
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002740-2
UR  - https://d-nb.info/1293660558/34
UR  - https://doi.org/10.18453/rosdok_id00002740
DO  - 10.18453/rosdok_id00002740
LA  - English
N1  - vorgelegt von Sven Adomeit
ID  - 1727955498
ER  -