TY - BOOK AU - Piehl, Patrick PY - 2019 DA - 2019// TI - Development of novel pincer catalysts for the synthesis of fine chemicals using hydrogen autotransfer reactions PB - Universität Rostock CY - Rostock AB - This thesis deals with the development of different homogeneous PNP pincer catalysts and their application in hydrogen autotransfer reactions. Manganese, rhenium and cyclometalated ruthenium complexes were used as catalysts for the α-alkylation of ketones with alcohols, a reaction creating new C‒C bonds while producing water as sole stochiometric by-product. This reaction was used for the alkylation of a broad scope of ketones including biologically relevant compounds like hormones with various alcohols. UR - http://purl.uni-rostock.de/rosdok/id00002703 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002703-6 UR - https://d-nb.info/1293660027/34 UR - https://doi.org/10.18453/rosdok_id00002703 DO - 10.18453/rosdok_id00002703 LA - English N1 - vorgelegt von Patrick Piehl ID - 1724113364 ER -