TY  - BOOK
AU  - Prymak, Iuliia
PY  - 2019
DA  - 2019//
TI  - New insights into the structure performance relationships of Ce-based catalysts for synthesis of organic carbonates using CO2
PB  - Universität Rostock
CY  - Rostock
AB  - This work focuses on the chemical utilization of CO2 in organic synthesis by means of direct carboxylation of C1-C2 alcohols (methanol and ethanol, respectively) to organic carbonates, e.g. dimethyl carbonate (DMC) and/or diethyl carbonate (DEC), over pure and P-modified Ce-Zr-O catalysts. The catalysts containing 80 mol% Ce and 20 mol% Zr exhibited the most efficient performance, which could be attributed to a good balance between the basic and acidic sites on its surface. The DMC yield was successfully improved further from 0.24% to 1.6% by phosphate modification of Ce0.8Zr0.2O2.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00002616
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002616-6
UR  - https://d-nb.info/1293658936/34
UR  - https://doi.org/10.18453/rosdok_id00002616
DO  - 10.18453/rosdok_id00002616
LA  - English
N1  - vorgelegt von Iuliia Prymak
ID  - 1689009152
ER  -