TY - BOOK AU - Scharnagl, Florian PY - 2019 DA - 2019// TI - Towards sustainability in hydrogenation and hydroformylation reactions PB - Universität Rostock CY - Rostock AB - The work focuses on the usage of the base-metal cobalt in order to endeavor a replacement of noble-metal based industrial and academic systems. An earlier published system for the cobalt-based hydrogenation of carbon dioxide was improved by ligand-modification to a 2.5-fold turnover number. Also, the activity of this system in the hydrogenation of organic carbonates to the corresponding alcohols was demonstrated for the first time. Besides, supported cobalt nanoparticles have been proven to be active for selective olefin hydrogenations and investigated for heterogeneous hydroformylations. UR - http://purl.uni-rostock.de/rosdok/id00002576 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002576-9 UR - https://d-nb.info/1293658316/34 UR - https://doi.org/10.18453/rosdok_id00002576 DO - 10.18453/rosdok_id00002576 LA - English N1 - vorgelegt von Florian Scharnagl ID - 1685629490 ER -