TY  - BOOK
AU  - Woźniak, Bartosz
PY  - 2018
DA  - 2018//
TI  - Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate
PB  - Universität Rostock
CY  - Rostock
AB  - This dissertation reports on the synthesis and applications of the biomass-derived 1-hydroxyhexane-2,5-dione (HHD). A new catalytic process was developed for the hydrogenation/hydrolytic ring opening of 5-hydroxymethylfurfural (5-HMF) resulting in the formation of HHD in good yields. Furthermore, HHD was converted to useful follow-up products including pyrroles and cyclopentanone derivatives. Additionally, readily accessible rhenium(VII) oxide was used for the catalytic deoxydehydration of renewable triols under solvent-free and aerobic conditions resulting in formation of the hydroxy-alkenes.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00002403
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002403-7
UR  - https://d-nb.info/1293655481/34
UR  - https://doi.org/10.18453/rosdok_id00002403
DO  - 10.18453/rosdok_id00002403
LA  - English
N1  - vorgelegt von Bartosz Wozniak
ID  - 1048999467
ER  -