TY - BOOK AU - Farrar Tobar, Ronald Alvaro PY - 2018 DA - 2018// TI - Selective hydrogenation and transfer hydrogenation reactions PB - Universität Rostock CY - Rostock AB - This dissertation describes the research on catalysts active for the selective transfer hydrogenation (TH) of α,β-unsaturated carbonyl compounds using EtOH as H2 source as alternative to commonly used iPrOH. Furthermore, a base-free iron-based protocol is designed and optimized for the novel TH of ester compounds using EtOH as H2 source. In addition, the chemical activity of new single rhodium atoms on Al2O3 is explored. Using limonene as a model compound, only the terminal olefin was hydrogenated and the potential selective character of the catalyst is highlighted. UR - http://purl.uni-rostock.de/rosdok/id00002389 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002389-1 UR - https://d-nb.info/1293655139/34 UR - https://doi.org/10.18453/rosdok_id00002389 DO - 10.18453/rosdok_id00002389 LA - English N1 - vorgelegt von Ronald Alvaro Farrar Tobar ID - 1047099071 ER -