TY  - BOOK
AU  - Jaime Treviño, Diego Alberto
PY  - 2017
DA  - 2017//
TI  - Selective oxidation of C16 macrocyclic diene to epoxides and ketones
PB  - Universität Rostock
CY  - Rostock
AB  - In the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00002353
UR  - https://doi.org/10.18453/rosdok_id00002353
DO  - 10.18453/rosdok_id00002353
LA  - English
N1  - vorgelegt von Lic. Diego A. Jaime Trevin̂o
ID  - 1042003475
ER  -