TY  - BOOK
AU  - Xia, Tian
PY  - 2018
DA  - 2018//
TI  - Isomerization of allylic alcohols to the ketones catalyzed by first-row transition metal pincer complexes
PB  - Universität Rostock
CY  - Rostock
AB  - This thesis mainly describes the isomerization of allylic and homo-allylic alcohols to the corresponding carbonyl compounds in the presence of inexpensive transition metal complexes. [Fe(PNP)(CO)HCl] (PNP=di-(2-diisopropylphosphanyl-ethyl)amine), activated in situ with KOtBu, is a highly active catalyst for the isomerization of allylic and homo-allylic alcohols to ketones without an external hydrogen supply. High reaction rates were obtained at 80 oC, but the catalyst is also sufficiently active at room temperature with most substrates.<eng>
UR  - http://purl.uni-rostock.de/rosdok/id00002267
UR  - https://nbn-resolving.org/urn:nbn:de:gbv:28-diss2018-0103-8
UR  - https://d-nb.info/1293652946/34
UR  - https://doi.org/10.18453/rosdok_id00002267
DO  - 10.18453/rosdok_id00002267
LA  - English
N1  - vorgelegt von Tian Xia
ID  - 1026618800
ER  -