TY - BOOK AU - Kale, Sumeet PY - 2016 DA - 2016// TI - Glycerol acetylation to triacetin over solid acid catalysts in liquid and gas phase PB - Universität Rostock CY - Rostock AB - The work focuses on the glycerol acetylation to triacetin over solid acid catalysts in liquid and gas phase. Acidic catalysts such as ion-exchange resins and supported heteropolyacids (HPA) were studied using toluene as an entrainer in batch-liquid phase. The high activity of catalysts depends on acidity and Keggin structure stabilization on the support. Low acidic catalysts like SiO2-based mixed metal oxides (TiO2, MgO, ZrO2, SrO and Sc2O3) were evaluated in continuous-gas phase. The high activity of SiO2-TiO2 catalyst seems to be related to the formation of Si-O-Ti bonds within the SiO2. UR - http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2018-0015-0 UR - https://nbn-resolving.org/urn:nbn:de:gbv:28-diss2018-0015-0 UR - https://d-nb.info/1293651435/34 UR - https://doi.org/10.18453/rosdok_id00002021 DO - 10.18453/rosdok_id00002021 LA - English N1 - vorgelegt von M. Sc. Sumeet S. Kale ID - 1016156642 ER -