Exploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro group
Gevorgyan, Ashot
1989-
aut
text
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Hochschulschrift
gw
2015
monographic
XA-DE
2015
eng
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The present work aimed to study the transition-metal-catalyzed direct C-H arylation of various nitro-substituted heteroarenes, including 4-nitroimidazole derivatives, 4-nitropyrazole derivatives, fused 3-nitropyridines, nitro-substituted pyrrole and thiophene. Under optimized reaction conditions a wide range of coupling partners were perfectly tolerated. Additional empirical studies indicated that the nitro group has influence on the regioselectivity of the reactions. In addition, the multipurpose nature of nitro group as a versatile directing group was explored.
vorgelegt von Ashot Gevorgyan
Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2015
547.215
547.64
540
35.50
http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0196-5
http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0196-5&pdf
http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0196-5
Exploration of transition-metal-catalyzed direct C-H arylation of nitro-substituted heteroarenes and further transformations of nitro group
2015
Druck-Ausgabe
(DE-627)839735235
Gevorgyan, Ashot, 1989 -
urn:nbn:de:gbv:28-diss2015-0196-5
935976261
rakwb
DE-627
151208
842372687
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