Synthesis of highly functionalized carbacycles, heterocycles and silylium-arene adducts by cyclocondensations, palladium catalyzed cross-coupling reactions and activation by [Me3Si]+ cation
Ibad, Muhammad Farooq
1982-
aut
text
theses
Text
Hochschulschrift
gw
2012
monographic
XA-DE
2012
eng
text/html
application/pdf
Online-Ressource graph. Darst.
The Me3SiOTf-mediated condensation of 1-ethoxy-2-fluoro-1,3-bis trimethylsilyloxy) 1,3-dienes with 3-cyanochromones afforded fluorinated azaxanthones or biaryls. The [4+2] cycloaddition of 1-ethoxy-2-fluoro-1,3-bis(trimethylsilyloxy)-1,3-diene with DMAD afforded dimethyl 4-fluoro-3,5-dihydroxyphthalate. Various arylated phthalates, naphthoates, indoles, are synthesized Pd(0)-catalyzed Suzuki cross-coupling reaction and studied. The experimental and theoretical study of the silylium arene adducts ([Me3Si-Ar][B(C6F5)4]) and the catalytic trimerisation of bissilylated diazomethane are studied.
vorgelegt von Muhammad Farooq Ibad
Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2012
35.49
http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2013-0037-7
http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2013-0037-7&pdf
http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2013-0037-7
Synthesis of highly functionalized carbacycles, heterocycles and silylium-arene adducts by cyclocondensations, palladium catalyzed cross-coupling reactions and activation by [Me3Si]+ cation
2012
Druck-Ausgabe
(DE-627)737908734
Ibad, Muhammad Farooq, 1982 -
urn:nbn:de:gbv:28-diss2013-0037-7
934994899
rakwb
DE-627
130325
739679139
20240717T195116.0
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