Palladium/di-1-adamantyl-n-butylphosphine-catalyzed carbonylation reactions
Brennführer, Anne
1981-
aut
text
theses
Text
Hochschulschrift
gw
2008
monographic
XA-DE
2008
eng
text/html
application/pdf
Online-Ressource graph. Darst.
Within this thesis several homogeneous palladium-catalyzed carbonylation reactions in the presence of carbon monoxide were investigated. In the course of our studies, the superior performance of the catalyst system palladium acetate/di-1-adamantyl-n-butylphosphine (cataCXium® A) in comparison to established palladium catalysts was demonstrated for both reductive carbonylations and alkoxycarbonylations of aryl and vinyl bromides. Hence, a variety of (hetero)aromatic aldehydes and carboxylic acid derivatives (esters, amides, acids) were successfully synthesized, among them novel biologically interesting indolylmaleimides. Furthermore, an efficient method for the synthesis of non-steroidal anti-inflammatory drugs such as ketoprofen and suprofen was developed.
Anne Brennführer
Enth. 6 Beitr. aus versch. Ztschr
Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2009
540
35.17
http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0110-5
http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0110-5&pdf
http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2009-0110-5
Palladium/di-1-adamantyl-n-butylphosphine-catalyzed carbonylation reactions
2008
Druck-Ausgabe
(DE-627)603369170
Brennführer, Anne, 1981 -
urn:nbn:de:gbv:28-diss2009-0110-5
455628128
rakwb
DE-627
090708
604071264
20240710T021248.0
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