Fischer, Steffen 1986- VerfasserIn aut Ludwig, Ralf 1961- AkademischeR BetreuerIn dgs Brückner, Angelika 1956- AkademischeR BetreuerIn dgs Universität Rostock Grad-verleihende Institution dgg Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät Grad-verleihende Institution dgg text theses Text Hochschulschrift gw 2021 monographic XA-DE Rostock Universität publisher 2021 Rostock Universitätsbibliothek distributor eng

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1 Online-Ressource Mechanistic investigation of three homogeneous, photochemical proton reduction systems that comprise Ir or Cu based photosensitizers and iron carbonyl catalysts to produce hydrogen. Operando IR spectroscopy coupled with gas volumetry was applied supported by other spectroscopic techniques. The rate determining steps, deactivation mechanisms and catalytic key species were determined, with the latter being a self-assembling [FeFe]-hydrogenase mimic in case phosphines are present as co-catalysts in the reaction mixture. These results lead to a better understanding and improvement of the systems.<eng> vorgelegt von Steffen Fischer Enthält Zeitschriftenartikel GutachterInnen: Ralf Ludwig (Universität Rostock, Institut für Chemie) ; Angelika Brückner (Leibniz-Institut für Katalyse e. V.) Dissertation Universität Rostock 2021 Kumulative Dissertation 500 540 541 540 35.17 http://purl.uni-rostock.de/rosdok/id00003292 https://doi.org/10.18453/rosdok_id00003292 https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00003292-2 https://d-nb.info/1293535222/34 Rostock, 2021

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Druck-Ausgabe (DE-627)1776241010 Fischer, Steffen, 1986 - urn:nbn:de:gbv:28-rosdok_id00003292-2 10.18453/rosdok_id00003292 1281997958 rda DE-627 211103 1775995003 20251226T195531.0 Converted from MARCXML to MODS version 3.8 using MARC21slim2MODS3-8_XSLT1-0.xsl (Revision 1.174 20250328) ger