Spectroscopic evidence for clusters of like-charged ions in ionic liquids
Strate, Anne
1987-
VerfasserIn
aut
Ludwig, Ralf
1961-
GutachterIn
oth
Winter, Roland
1954-
GutachterIn
oth
Universität Rostock
Grad verleihende Institution
dgg
Universität Rostock
Mathematisch-Naturwissenschaftliche Fakultät
Grad verleihende Institution
dgg
text
theses
Text
Hochschulschrift
gw
2017
monographic
XA-DE
Rostock
University
publisher
2017
eng
1 Online-Ressource
In this work the counterintuitive phenomenon of attraction between ions of like charge is described for ionic liquids. It is based on cooperative hydrogen bonding leading to different sized cationic clusters. Experimentally these clusters are indicated by characteristic spectroscopic features like e.g. redshifts of OH vibrational frequencies. The experimental observables can be related to charge transfer and second order stabilization energy. Finally, a theoretical approach of stabilizing the cationic cluster network by either neutral molecules or negatively charged counterions has been done.<eng>
submitted by Dipl. Chem. Anne Strate, née Knorr
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Kumulative Dissertation Universität Rostock 2017
540
541
540
Physikalische Chemie
http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2018-0055-3
https://doi.org/10.18453/rosdok_id00002061
https://nbn-resolving.org/urn:nbn:de:gbv:28-diss2018-0055-3
https://d-nb.info/129365213X/34
Spectroscopic evidence for clusters of like-charged ions in ionic liquids
Rostock : University, 2017
Druck-Ausgabe
(DE-627)1007270438
Strate, Anne, 1987 -
urn:nbn:de:gbv:28-diss2018-0055-3
10.18453/rosdok_id00002061
1031377157
rda
DE-627
180416
1018696172
20251224T211612.0
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