%0 Book
%T Synthesis and characterisation of cyclic polyphosphanes
%A Bresien, Jonas
%D 2016
%C Rostock
%C Universität Rostock
%G English
%F 865466955
%O submitted by Jonas Bresien
%O Enthält Beiträge aus verschiedenen Zeitschriften
%O Cumulative Dissertation Universität Rostock 2016
%X The synthesis and reactivity of the novel cyclotetraphosphane [ClP(μ-PMes*)]2 were studied. The cyclophosphane proved to be a versatile reagent in phosphorus chemistry, since its Cl-functionalised P4 backbone could be used as a building block in a variety of reactions with Lewis acids, bases as well as reducing agents. The rearrangement of P−P bonds as well as a 1,2-Cl shift were identified as common reaction pathways to stabilise the products. All synthesised compounds were fully characterised, including experimental and theoretical methods.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%U http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2016-0091-5