%0 Book %T Synthesis of functionalized isatins, benzoxazoles, isoflavones, coumarins, by site-selective Suzuki-Miyaura cross-coupling reactions %A Al-Abo, Aws Mardan Hamdy %D 2015 %G English %F 842372172 %O vorgelegt von M.Sc. Aws Mardan Hamdy Al-Abo %O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2015 %X This thesis includes regioselective palladium catalyzed Suzuki-Miyaura cross coupling reactions of isatins benzoxazols isoflavones and coumarins. These classes of compounds are of pharmacological relevance. Suzuki-Miyaura cross-coupling reactions of dichloro methylindolinen dione afforded arylated isatins. The reactions proceeded with very good site selectivity. The Suzuki-Miyaura reaction of dichlorobenzoxazol, of the bis(triflate) of dihydroxyisoflavone, and of the bis(triflate) of methyl dihydroxycoumarin, with different boronic acids, gave the corresponding site-selective mono-arylated, homo bis-arylated and mixed bis-arylated derivaties, most of them with very good site-selectivity. %L 547.27 %9 theses %9 Text %9 Hochschulschrift %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0197-1 %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0197-1&pdf %U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0197-1