%0 Book
%T Asymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefins
%A Domke, Lutz
%D 2014
%G English
%F 817979794
%O vorgelegt von Lutz Domke
%O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2014
%X Asymmetric hydrogenation as well as hydroformylation of 1,1-disubstituted olefins were investigated. Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high stereoselectivities. Furthermore, the rhodium-catalyzed asymmetric hydroformylation of an alpha-phosphorylated styrene derivative was examined and the scope could be expanded using new phosphite-phosphoramidite ligands. In addition, HP-NMR experiments gave some indication of the active catalyst-complex.
%L 547.2
%9 theses
%9 Text
%9 Hochschulschrift
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0026-6
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0026-6&pdf
%U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0026-6