%0 Book
%T Synthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactions
%A Thiel, Indre
%D 2013
%G English
%F 779460162
%O Indre Thiel
%O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2013
%X This thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands – namely an olefin and a phosphite ligand – proved to be superior to the homoleptic equivalents, providing sufficient activity in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further modifications resulted in air-stable and recyclable catalysts, which could be supported on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.
%L 546.62325
%9 theses
%9 Text
%9 Hochschulschrift
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2014-0044-1
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2014-0044-1&pdf
%U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2014-0044-1