%0 Book
%T Development of new homogeneous (enantioselective) hydrogenation catalysts based on bio-relevant metals
%A Zhou, Shaolin
%D 2011
%G English
%F 66775279X
%O vorgelegt von Shaolin Zhou
%O Die elektronische Ausgabe weicht von der gedruckten ab. Die gedruckte enthält Beiträge aus verschiedenen Zeitschriften
%O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2011
%X This thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Brønsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. Finally, an iron cluster catalyst was discovered to catalyze the reduction of amides with inexpensive PMHS.
%L 35.69
%9 theses
%9 Text
%9 Hochschulschrift
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7&pdf
%U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0127-7