%0 Book %T Synthesis of 1-alkenylpyrenes and of fluorinated arenes by palladium(0)-catalyzed cross-coupling reactions and photophysical properties of the products %A Sharif Akbar, Muhammad %D 2011 %G English %F 666752982 %O vorgelegt von Muhammad Sharif Akbar %O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2011 %X The palladium(0)-catalyzed Heck cross coupling reactions of 1-bromopyrene provided functionalized alkenylpyrenes with styrenes and acrylates by single fold Heck reactions. Suzuki-Miyaura cross coupling reactions of the differently substituted di and mono fluoro benzenes with different arylboronic acids afforded fluoro-substituted terphenyls with excellent site-selectivity. Sonogashira and Suzuki-Miyaura coupling reactions of 1,2-difluoro, 1,3-difluoro, 1,4-difluoro, 1-fluoro, tetraiodobenzenes and pentaiodobenzenes respectively provided tetra- and penta-alkynylated and arylbenzene products. %L 540 %9 theses %9 Text %9 Hochschulschrift %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0126-1 %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0126-1&pdf %U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0126-1