%0 Book %T Synthesis of substituted dibenzothiophenes, pyrazines, quinoxalines, flavones, pyrimidines and furans by regioselective palladium (0)-catalyzed cross-coupling reactions %A Malik, Imran %D 2010 %G English %F 646972782 %O vorgelegt von Imran Malik %O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2010 %O Online-Ausg.: %O [Online-Ausg.] %O Reproduktion 2011 [Online-Ausg.] Online-Ausg.: |2011|||||||||| %O Langzeitarchivierung gewährleistet pdager %X The palladium(0)-catalyzed Heck reactions of brominated benzothiophene provided functionalized dibenzothiophenes by 6p-electro cyclization reactions. Heck reactions of dichloropyrazine and quinoxaline provided dialkenyl-, 2-alkenyl-3-alkyl and dialkylpyrazines and quinoxalines. Suzuki-Miyaura reactions of the bis(triflate) of 7,8- dihyroxyflavone with arylboronic acids afforded aryl-substituted flavones with excellent site-selectivity. Sonogashira reactions of tetrachloropyrimidine and tetrabromofuran provided di-, tri-, tetra-alkynylated and mixed Sonogashira-Suzuki products with excellent fluorescence properties. %L 540 %9 theses %9 Text %9 Hochschulschrift %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0030-7 %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0030-7&pdf %U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0030-7 %U http://d-nb.info/1013687884/34 %U http://rosdok.uni-rostock.de/file/rosdok_derivate_000000004557/Dissertation_Malik_2011.pdf