%0 Book %T calorimetric study of non-equilibrium structures on fast cooling (100 000 K/s) %A Adamovski, Serguei %D 2010 %G English %F 642884315 %O submitted by Serguei Adamovski %O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2010 %O Langzeitarchivierung gewährleistet pdager %X Present work describes an ultra-fast scanning calorimeter that is capable of controlled cooling and heating at rates up to 100 000 K/s as well as isothermal measurements with time resolution of 0.1 ms. The technique was applied to study crystallization kinetics of polymers and monodisperse n-alkanes. It is shown that the bend in the isothermal crystallization kinetics curve of n-alkanes is not the transition between formations of structures with different folding indexes, but it is rather caused by the interplay of different processes with different kinetics as well as a self-poisoning effect. %L 536.63 %9 theses %9 Text %9 Hochschulschrift %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0196-0 %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0196-0&pdf %U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2010-0196-0 %U http://d-nb.info/1011895897/34 %U http://rosdok.uni-rostock.de/metadata/rosdok_disshab_000000000563