%0 Book %T Hydrogen generation from renewable resources %A Loges, Björn %D 2009 %G English %F 616990170 %O vorgelegt von Björn Loges %O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2009 %X Hydrogen generation from 2-propanol and formic acid and its direct use in fuel cells was studied. 2-propanol was dehydrogenated with ruthenium diamine catalysts. Formic acid was decomposed selectively to hydrogen and carbon dioxide in a system containing ruthenium catalysts and formic acid amine adducts. The best catalyst activity and productivity were achieved with in situ generated ruthenium phosphine catalysts, e.g. [RuCl2(benzene)]2 / dppe (TOF = 900 h-1, TON = 260.000). The influence of irradiation with visible light has been described for the ruthenium phosphine catalysts. %L 540 %9 theses %9 Text %9 Hochschulschrift %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0017-1 %U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0017-1&pdf %U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2010-0017-1 %U http://rosdok.uni-rostock.de/metadata/rosdok_disshab_000000000384 %U http://d-nb.info/1001051432/34