%0 Book
%T Application of novel phosphine ligands in palladium-catalyzed cross-coupling reactions
%A Torborg, Christian
%D 2009
%G English
%F 610628437
%O vorgelegt von Christian Torborg
%O Enth. 5 Beitr. aus versch. Ztschr
%O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2009
%X This thesis describes the application of 2-phosphino-N-aryl-heterocycles as ligands in Pd-catalyzed CC, CN and CO bond forming reactions. Based on prior studies, 2-phosphino-N-arylindoles and -pyrrols were found to form efficient catalysts with Pd-salts in the Sonogashira coupling of (hetero)aryl bromides and the Pd-catalyzed monoarylation of ammonia. The novel imidazole-based phosphines were prepared after a modular synthesis and are stable towards air. They were employed in the Pd-catalyzed phenol synthesis, the Heck-Cassar coupling, and the Pd-catalyzed monoarylation of ammonia. Furthermore, mechanistic studies in the Pd-catalyzed hydroxylation were undertaken.
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3&pdf
%U http://rosdok.uni-rostock.de/file/rosdok_derivate_000000004073/Dissertation_Torborg_2009.pdf
%U http://d-nb.info/999072188/34
%U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2009-0174-3